d4280641-c996-487f-86e3-9406f73ad2d1C-6 fluorinated acrylic copolymerEsterification of 2-(Perfluorohexyl)ethanol by acrylic acidsingle route, at producerMW=418.15 g/mol1H,1H,2H,2H-Perfluorooctyl acrylate, Tridecafluoro-n-octyl Acrylate
CAS: 17527-29-6SystemsPaints and chemical preparationsThe data set covers all relevant process steps / technologies over the supply chain of the represented cradle to gate inventory with a good overall data quality. The inventory is mainly based on industry data and is completed, where necessary, by secondary data. Please add additional docu summary sentence.0 The data set represents United States specific situation, focusing on the main technologies, the region specific characteristics and / or import statistics.Foreground system:
2-(Perfluorohexyl)ethanol is esterified with acrylic acid, using sulfuric acid as catalyzer and hydroquinone as acrylic acid polymerization inhibitor. The water formed is separated through the top of an azeotropic-distillation column. The reaction conditions are: atmospheric pressure, temperature 85 – 95°C, reaction time 3 – 5 h, molar ratio (alcohol to acid) 1.0 – 1.1.
After completion of the esterification, the reaction liquid is cooled to 60°C and then transferred to a tank where the sulfuric acid is neutralized with alkali. The oil and water layers are separated and stored. The oil layer is fed into a solvent-recovery column and subsequently into an alcohol-recovery column for distillation. The solvent and alcohol are recovered overhead and reused in the reaction.
The crude ester obtained from the bottom of the alcohol-recovery column is fed into the product column where purified acrylic ester is obtained by distillation. The bottom liquid mainly is recycled to the reactor and the alcohol-recovery column to be reused as supplementary inhibitor. However, part of the liquid is fed into the bottom stripper (i) to recover valuable materials that are resupplied to the product column. High-boiling waste composed of polymers, inhibitors, and other impurities is taken out of the bottom stripper and incinerated.
The water from the water-layer tank is fed into the organic stripper together with the water layer from the top and the bottom of the solvent-recovery column. The oil layer obtained from the top of the solvent-recovery column is recycled into the oil-layer tank. The waste obtained from the bottom of the organic stripper is incinerated after concentration.
The yield reaches 95 % and 96 % based on acrylic acid and on alcohol, respectively. The purity of the product exceeds 99.5 wt %.
Precursor materials:
2-(Perfluorohexyl)ethanol: Hydrolysis of 2-(Perfluorohexyl)ethyl iodide with NaOH 50% in water, yielding 2-(Perfluorohexyl)ethanol and sodium iodide. -> Substitution is favored over elimination by lower temperatures, more dilute solutions of sodium hydroxide and more water in the solvent mixture.
Pentafluoroiodoethane: Addition of tetrafluoroethylene (TFE) to Perfluoroethyl iodide by telomerization, Initiator IF5
Assumption: 100% TFE conversion, C15+ higher-molecular weight perfluoroalkyl iodides incinerated (worst-case scenario)
Input/output material quantities are taken from US 3132185 A, example 1:
"Example I 167.7 parts (0.66 mol) of iodine, 73.3 parts (0.33 mol) of iodine pentafluoride and 0.5 part (0.0028 mol; i.e., 8.48 millimols/mol IE of antimony trifluoride were mixed at ambient temperature in a HastelloyC lined autoclave (2 mols ofiodine and 8.48 millimols of catalyst per mol of iodine pentafluoride). The autoclave was cooled below 0 C., evacuated to remove air and heated to 80 C. with agitation.
Tetrafluoroethylene was added slowly, with agitation, in small increments (2 parts initially, increased to 5 parts and then to parts as the reaction proceeded) to the autoclave until a total of 192 parts had been added (one hour required). The pressure rose to about 200-250 p.s.i.g. after each addition and dropped to less than 100 p.s.i.g.- in less than three minutes. The temperature rose 8 to 26 C. after each addition in about one minute-and then reverted to about 80 C. until 165 parts (5 mols per mol of iodine pentafluoride) had been added. There was no temperature increase during the addition of the remaining 27 parts of 'tetrafluoroethylene. The pressure steadily increased with no sign of any decrease, indicating that the reaction was complete when 165 parts had been added. The reaction mass was held at 80 C. for one hour without any further reaction.
After cooling, the volatile products were vented from the autoclave at 60 C. through a water scrubber and a Drierite, (calcium sulfate) column and ethylene, 0.6% perfluorocyclobutane, 0.7% collected ina refrigerated receiver at -60 C. Analysis of the condensed product (397 parts) by mass spectrometer showed 98.3% perfluoroethyl iodide, 0.4% unreacted tetrafluoroethylene, 0.8% 1,2-diiodotetrofluoroethane and 0.4% perfluorocyclobutane. The noncondensed gases were collected and found to contain 28.1 parts of unreacted tetrafluoroethylene and 4.3 parts of perfluoroethyl iodide. There was no organic residue in the autoclave. The yield of pentafluoroethyl iodide was 98.5% based on the quantity of tetrafluoroethylene consumed; halogen conversion was quantitative"
2-(Perfluorohexyl)ethyl iodide: Radical-catalysed addition of ethylene to Perfluorohexyl iodide. Free radicals are initiated by t-butyl peroxide. Assumption: 95% yield, residues incinerated (worst-case scenario)
n-Perfluorohexyl iodide and Pentafluoroiodoethane : Addition of tetrafluoroethylene (TFE) to Perfluoroethyl iodide by telomerization, Initiator IF5. Assumption: 100% TFE conversion, C15+ higher-molecular weight perfluoroalkyl iodides incinerated (worst-case scenario)
Background system:
Electricity: Electricity is modelled according to the individual country-specific situations. The country-specific modelling is achieved on multiple levels. Firstly, individual energy carrier specific power plants and plants for renewable energy sources are modelled according to the current national electricity grid mix. Modelling the electricity consumption mix includes transmission / distribution losses and the own use by energy producers (own consumption of power plants and "other" own consumption e.g. due to pumped storage hydro power etc.), as well as imported electricity. Secondly, the national emission and efficiency standards of the power plants are modelled as well as the share of electricity plants and combined heat and power plants (CHP). Thirdly, the country-specific energy carrier supply (share of imports and / or domestic supply) including the country-specific energy carrier properties (e.g. element and energy content) are accounted for. Fourthly, the exploration, mining/production, processing and transport processes of the energy carrier supply chains are modelled according to the specific situation of each electricity producing country. The different production and processing techniques (emissions and efficiencies) in the different energy producing countries are considered, e.g. different crude oil production technologies or different flaring rates at the oil platforms.
Thermal energy, process steam: The thermal energy and process steam supply is modelled according to the individual country-specific situation with regard to emission standards and considered energy carriers. The thermal energy and process steam are produced at heat plants. Efficiencies for thermal energy production are by definition 100% in relation to the corresponding energy carrier input. For process steam the efficiency ranges from 85%, 90% to 95%. The energy carriers used for the generation of thermal energy and process steam are modelled according to the specific import situation (see electricity above).
Transports: All relevant and known transport processes are included. Ocean-going and inland ship transport as well as rail, truck and pipeline transport of bulk commodities are considered.
Energy carriers: The energy carriers are modelled according to the specific supply situation (see electricity above).
Refinery products: Diesel fuel, gasoline, technical gases, fuel oils, lubricants and residues such as bitumen are modelled with a parameterised country-specific refinery model. The refinery model represents the current national standard in refining techniques (e.g. emission level, internal energy consumption, etc.) as well as the individual country-specific product output spectrum, which can be quite different from country to country. The supply of crude oil is modelled, again, according to the country-specific situation with the respective properties of the resources.Electricity grid mixProcess steam from natural gas 95%Acrylic acid (Propene)Hydroquinone (oxidation P-DIPB)Water deionizedSodium hydroxide mix (50%)Ethene (ethylene)Butyl peroxideThe product will be used as a water and oil repellent coating for textiles. It can be either directly applied and dried, or polymerized by curing after impregnation for a more robust coating.Organic Intermediate_2 (Perfluorohexyl)ethylacrylate.JPGLCI resultAttributionalNoneAllocation - market valueAllocation - net calorific valueAllocation - exergetic contentAllocation - massNot applicableForeground system: No allocation
Background system: For the combined heat and power production, allocation by exergetic content is applied. For the electricity generation and by-products, e.g. gypsum, allocation by market value is applied due to no common physical properties. Within the refinery allocation by net calorific value and mass is used. For the combined crude oil, natural gas and natural gas liquids production allocation by net calorific value is applied.
For details please see the document "GaBi Databases Modelling Principles"All data used in the calculation of the LCI results refer to net calorific value.NoneGaBi Modelling PrinciplesGaBi Water Modelling PrinciplesCut-off rules for each unit process: Coverage of at least 95 % of mass and energy of the input and output flows, and 98 % of their environmental relevance (according to expert judgement).
For further details please see the document "GaBi Databases Modelling Principles"None-Material inputs and outputs calculated stoechiometrically, assuming a purity of 99.5% and 0.5% organic waste output to incineration
-Water, electricity and steam inputs were estimated using expert knowledge
For details please see the document "GaBi Databases Modelling Principles"NoneFor details please see the document "GaBi Databases Modelling Principles"NoneULLMANN'S Encyclopedia of Industrial ChemistryRoempp Lexikon - Lacke und Druckfarben, 1997Individual industry dataIndustrial Inorganic Chemistry, 2000Industrial Organic Chemistry, 2003Plastics Europe Association of Plastics Manufacturers, 2006Acrylic Acid and DerivativesDupont Capstone 62-MA datasheetAlternative Fluoropolymers to Avoid the Challenges Associated with Perfluorooctanoic AcidAsahi Guard product information95.0n/an/anoneThe data set represents a cradle to gate inventory. It can be used to characterise the supply chain situation of the respective commodity in a representative manner. Combination with individual unit processes using this commodity enables the generation of user-specific (product) LCAs.No statementAnthropogenic Abiotic Depletion Potential (AADP), TU BerlinCML2001 - Jan. 2016, Abiotic Depletion (ADP elements)CML2001 - Jan. 2016, Abiotic Depletion (ADP fossil)CML2001 - Jan. 2016, Acidification Potential (AP)CML2001 - Jan. 2016, Eutrophication Potential (EP)CML2001 - Jan. 2016, Freshwater Aquatic Ecotoxicity Pot. (FAETP inf.)CML2001 - Jan. 2016, Global Warming Potential (GWP 100 years)CML2001 - Jan. 2016, Global Warming Potential (GWP 100 years), excl biogenic carbonCML2001 - Jan. 2016, Human Toxicity Potential (HTP inf.)CML2001 - Jan. 2016, Marine Aquatic Ecotoxicity Pot. (MAETP inf.)CML2001 - Jan. 2016, Ozone Layer Depletion Potential (ODP, steady state)CML2001 - Jan. 2016, Photochem. Ozone Creation Potential (POCP)CML2001 - Jan. 2016, Terrestric Ecotoxicity Potential (TETP inf.)CML2001 - Jan. 2016, Global Warming Potential (GWP 100), excl bio. C, incl LUC, no norm/weightCML2001 - Jan. 2016, Global Warming Potential (GWP 100), incl bio. C, incl LUC, no norm/weightCML2001 - Jan. 2016, Global Warming Potential (GWP 100), Land Use Change only, no norm/weightCML2001 - Jan. 2016, Abiotic Depletion (ADP elements), Economic ReserveCML2001 - Jan. 2016, Abiotic Depletion (ADP elements), Reserve BaseEF 2.0 Acidification terrestrial and freshwaterEF 2.0 Cancer human health effectsEF 2.0 Climate ChangeEF 2.0 Ecotoxicity freshwaterEF 2.0 Eutrophication freshwaterEF 2.0 Eutrophication marineEF 2.0 Eutrophication terrestrialEF 2.0 Ionising radiation - human healthEF 2.0 Land UseEF 2.0 Non-cancer human health effectsEF 2.0 Ozone depletionEF 2.0 Photochemical ozone formation - human healthEF 2.0 Resource use, energy carriersEF 2.0 Resource use, mineral and metalsEF 2.0 Respiratory inorganicsEF 2.0 Water scarcityReCiPe 2016 v1.1 Midpoint (E) - Terrestrial ecotoxicityReCiPe 2016 v1.1 Midpoint (E) - Freshwater ecotoxicityReCiPe 2016 v1.1 Midpoint (E) - Marine ecotoxicityReCiPe 2016 v1.1 Midpoint (E) - Human toxicity, non-cancerReCiPe 2016 v1.1 Midpoint (E) - Human toxicity, cancerReCiPe 2016 v1.1 Midpoint (E) - Climate change, incl biogenic carbonReCiPe 2016 v1.1 Midpoint (E) - Climate change, default, excl biogenic carbonReCiPe 2016 v1.1 Midpoint (E) - Metal depletionReCiPe 2016 v1.1 Midpoint (E) - Photochemical Ozone Formation, Human HealthReCiPe 2016 v1.1 Midpoint (E) - Photochemical Ozone Formation, EcosystemsReCiPe 2016 v1.1 Midpoint (E) - Fossil depletionReCiPe 2016 v1.1 Midpoint (E) - Freshwater ConsumptionReCiPe 2016 v1.1 Midpoint (E) - Stratospheric Ozone DepletionReCiPe 2016 v1.1 Midpoint (E) - Fine Particulate Matter FormationReCiPe 2016 v1.1 Midpoint (E) - Terrestrial AcidificationReCiPe 2016 v1.1 Midpoint (E) - Ionizing RadiationReCiPe 2016 v1.1 Midpoint (E) - Freshwater EutrophicationReCiPe 2016 v1.1 Midpoint (E) - Land useReCiPe 2016 v1.1 Midpoint (E) - Marine EutrophicationReCiPe 2016 v1.1 Midpoint (E) - Climate change, excl biog. C, incl LUC, no norm/weightReCiPe 2016 v1.1 Midpoint (E) - Climate change, incl biog. C, incl LUC, no norm/weightReCiPe 2016 v1.1 Endpt(E) - Climate change Terrest Ecosystems, excl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(E) - Climate change Human Health, excl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(E) - Climate change Freshw Ecosystems, excl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(E) - Climate change Terrest Ecosystems, incl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(E) - Climate change Human Health, incl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(E) - Climate change Freshw Ecosystems, incl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(E) - Climate change Freshw Ecosystems, LUC only, no norm/weightReCiPe 2016 v1.1 Endpt(E) - Climate change Human Health, LUC only, no norm/weightReCiPe 2016 v1.1 Midpoint (E) - Climate change, LUC only, no norm/weightReCiPe 2016 v1.1 Endpt(E) - Climate change Terrest Ecosystems, LUC only, no norm/weightReCiPe 2016 v1.1 Endpoint (E) - Terrestrial ecotoxicityReCiPe 2016 v1.1 Endpoint (E) - Freshwater ecotoxicityReCiPe 2016 v1.1 Endpoint (E) - Marine ecotoxicityReCiPe 2016 v1.1 Endpoint (E) - Human toxicity, non-cancerReCiPe 2016 v1.1 Endpoint (E) - Human toxicity, cancerReCiPe 2016 v1.1 Endpoint (E) - Climate change Freshw Ecosystems, default, excl biogenic carbonReCiPe 2016 v1.1 Endpoint (E) - Climate change Human Health, default, excl biogenic carbonReCiPe 2016 v1.1 Endpoint (E) - Climate change Terrest Ecosystems, default, excl biogenic carbonReCiPe 2016 v1.1 Endpoint (E) - Climate change Terrest Ecosystems, incl biogenic carbonReCiPe 2016 v1.1 Endpoint (E) - Climate Change Human Health, incl biogenic carbonReCiPe 2016 v1.1 Endpoint (E) - Climate change Freshw Ecosystems, incl biogenic carbonReCiPe 2016 v1.1 Endpoint (E) - Metal depletionReCiPe 2016 v1.1 Endpoint (E) - Photochemical Ozone Formation, Human HealthReCiPe 2016 v1.1 Endpoint (E) - Photochemical Ozone Formation, EcosystemsReCiPe 2016 v1.1 Endpoint (E) - Fossil depletionReCiPe 2016 v1.1 Endpoint (E) - Freshwater Consumption, Human HealthReCiPe 2016 v1.1 Endpoint (E) - Freshwater Consumption, Terrest EcosystemsReCiPe 2016 v1.1 Endpoint (E) - Freshwater Consumption, Freshw EcosystemsReCiPe 2016 v1.1 Endpoint (E) - Stratospheric Ozone DepletionReCiPe 2016 v1.1 Endpoint (E) - Fine Particulate Matter FormationReCiPe 2016 v1.1 Endpoint (E) - Terrestrial AcidificationReCiPe 2016 v1.1 Endpoint (E) - Ionizing RadiationReCiPe 2016 v1.1 Endpoint (E) - Freshwater EutrophicationReCiPe 2016 v1.1 Endpoint (E) - Land useReCiPe 2016 v1.1 Endpoint (E) - Marine EutrophicationReCiPe 2016 v1.1 Midpoint (H) - Terrestrial ecotoxicityReCiPe 2016 v1.1 Midpoint (H) - Freshwater ecotoxicityReCiPe 2016 v1.1 Midpoint (H) - Marine ecotoxicityReCiPe 2016 v1.1 Midpoint (H) - Human toxicity, non-cancerReCiPe 2016 v1.1 Midpoint (H) - Human toxicity, cancerReCiPe 2016 v1.1 Midpoint (H) - Climate change, default, excl biogenic carbonReCiPe 2016 v1.1 Midpoint (H) - Climate change, incl biogenic carbonReCiPe 2016 v1.1 Midpoint (H) - Metal depletionReCiPe 2016 v1.1 Midpoint (H) - Photochemical Ozone Formation, Human HealthReCiPe 2016 v1.1 Midpoint (H) - Photochemical Ozone Formation, EcosystemsReCiPe 2016 v1.1 Midpoint (H) - Fossil depletionReCiPe 2016 v1.1 Midpoint (H) - Freshwater ConsumptionReCiPe 2016 v1.1 Midpoint (H) - Stratospheric Ozone DepletionReCiPe 2016 v1.1 Midpoint (H) - Fine Particulate Matter FormationReCiPe 2016 v1.1 Midpoint (H) - Terrestrial AcidificationReCiPe 2016 v1.1 Midpoint (H) - Ionizing RadiationReCiPe 2016 v1.1 Midpoint (H) - Freshwater EutrophicationReCiPe 2016 v1.1 Midpoint (H) - Land useReCiPe 2016 v1.1 Midpoint (H) - Marine EutrophicationReCiPe 2016 v1.1 Midpoint (H) - Climate change, excl biog. C, incl LUC, no norm/weightReCiPe 2016 v1.1 Endpt(H) - Climate change Terrest Ecosystems, excl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(H) - Climate change Human Health, excl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(H) - Climate change Freshw Ecosystems, excl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Midpoint (H) - Climate change, incl biog. C, incl LUC, no norm/weightReCiPe 2016 v1.1 Endpt(H) - Climate change Terrest Ecosystems, incl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(H) - Climate change Human Health, incl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(H) - Climate change Freshw Ecosystems, incl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(H) - Climate change Freshw Ecosystems, LUC only, no norm/weightReCiPe 2016 v1.1 Endpt(H) - Climate change Human Health, LUC only, no norm/weightReCiPe 2016 v1.1 Midpoint (H) - Climate change, LUC only, no norm/weightReCiPe 2016 v1.1 Endpt(H) - Climate change Terrest Ecosystems, LUC only, no norm/weightReCiPe 2016 v1.1 Endpoint (H) - Terrestrial ecotoxicityReCiPe 2016 v1.1 Endpoint (H) - Freshwater ecotoxicityReCiPe 2016 v1.1 Endpoint (H) - Marine ecotoxicityReCiPe 2016 v1.1 Endpoint (H) - Human toxicity, non-cancerReCiPe 2016 v1.1 Endpoint (H) - Human toxicity, cancerReCiPe 2016 v1.1 Endpoint (H) - Climate change Freshw Ecosystems, default, excl biogenic carbonReCiPe 2016 v1.1 Endpoint (H) - Climate change Human Health, default, excl biogenic carbonReCiPe 2016 v1.1 Endpoint (H) - Climate change Terrest Ecosystems, default, excl biogenic carbonReCiPe 2016 v1.1 Endpoint (H) - Climate change Terrest Ecosystems, incl biogenic carbonReCiPe 2016 v1.1 Endpoint (H) - Climate change Human Health, incl biogenic carbonReCiPe 2016 v1.1 Endpoint (H) - Climate change Freshw Ecosystems, incl biogenic carbonReCiPe 2016 v1.1 Endpoint (H) - Metal depletionReCiPe 2016 v1.1 Endpoint (H) - Photochemical Ozone Formation, Human HealthReCiPe 2016 v1.1 Endpoint (H) - Photochemical Ozone Formation, EcosystemsReCiPe 2016 v1.1 Endpoint (H) - Fossil depletionReCiPe 2016 v1.1 Endpoint (H) - Freshwater Consumption, Human HealthReCiPe 2016 v1.1 Endpoint (H) - Freshwater Consumption, Terrest EcosystemsReCiPe 2016 v1.1 Endpoint (H) - Freshwater Consumption, Freshw EcosystemsReCiPe 2016 v1.1 Endpoint (H) - Stratospheric Ozone DepletionReCiPe 2016 v1.1 Endpoint (H) - Fine Particulate Matter FormationReCiPe 2016 v1.1 Endpoint (H) - Terrestrial AcidificationReCiPe 2016 v1.1 Endpoint (H) - Ionizing RadiationReCiPe 2016 v1.1 Endpoint (H) - Freshwater EutrophicationReCiPe 2016 v1.1 Endpoint (H) - Land useReCiPe 2016 v1.1 Endpoint (H) - Marine EutrophicationReCiPe 2016 v1.1 Midpoint (I) - Terrestrial ecotoxicityReCiPe 2016 v1.1 Midpoint (I) - Freshwater ecotoxicityReCiPe 2016 v1.1 Midpoint (I) - Marine ecotoxicityReCiPe 2016 v1.1 Midpoint (I) - Human toxicity, non-cancerReCiPe 2016 v1.1 Midpoint (I) - Climate change, default, excl biogenic carbonReCiPe 2016 v1.1 Midpoint (I) - Climate change, incl biogenic carbonReCiPe 2016 v1.1 Midpoint (I) - Metal depletionReCiPe 2016 v1.1 Midpoint (I) - Photochemical Ozone Formation, Human HealthReCiPe 2016 v1.1 Midpoint (I) - Photochemical Ozone Formation, EcosystemsReCiPe 2016 v1.1 Midpoint (I) - Fossil depletionReCiPe 2016 v1.1 Midpoint (I) - Human toxicity, cancerReCiPe 2016 v1.1 Midpoint (I) - Freshwater ConsumptionReCiPe 2016 v1.1 Midpoint (I) - Stratospheric Ozone DepletionReCiPe 2016 v1.1 Midpoint (I) - Fine Particulate Matter FormationReCiPe 2016 v1.1 Midpoint (I) - Terrestrial AcidificationReCiPe 2016 v1.1 Midpoint (I) - Ionizing RadiationReCiPe 2016 v1.1 Midpoint (I) - Freshwater EutrophicationReCiPe 2016 v1.1 Midpoint (I) - Land useReCiPe 2016 v1.1 Midpoint (I) - Marine EutrophicationReCiPe 2016 v1.1 Midpoint (I) - Climate change, excl biog. C, incl LUC, no norm/weightReCiPe 2016 v1.1 Endpt(I) - Climate change Terrest Ecosystems, excl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(I) - Climate change Human Health, excl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(I) - Climate change Freshw Ecosystems, excl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Midpoint (I) - Climate change, incl biog. C, incl LUC, no norm/weightReCiPe 2016 v1.1 Endpt(I) - Climate change Terrest Ecosystems, incl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(I) - Climate change Human Health, incl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(I) - Climate change Freshw Ecosystems, incl biog. C, incl LUC, no norm/weighReCiPe 2016 v1.1 Endpt(I) - Climate change Freshw Ecosystems, LUC only, no norm/weightReCiPe 2016 v1.1 Endpt(I) - Climate change Human Health, LUC only, no norm/weightReCiPe 2016 v1.1 Midpoint (I) - Climate change, LUC only, no norm/weightReCiPe 2016 v1.1 Endpt(I) - Climate change Terrest Ecosystems, LUC only, no norm/weightReCiPe 2016 v1.1 Endpoint (I) - Terrestrial ecotoxicityReCiPe 2016 v1.1 Endpoint (I) - Freshwater ecotoxicityReCiPe 2016 v1.1 Endpoint (I) - Marine ecotoxicityReCiPe 2016 v1.1 Endpoint (I) - Human toxicity, non-cancerReCiPe 2016 v1.1 Endpoint (I) - Climate change Freshw Ecosystems, default, excl biogenic carbonReCiPe 2016 v1.1 Endpoint (I) - Climate change Human Health, default, excl biogenic carbonReCiPe 2016 v1.1 Endpoint (I) - Climate change Terrest Ecosystems, default, excl biogenic carbonReCiPe 2016 v1.1 Endpoint (I) - Climate change Terrest Ecosystems, incl biogenic carbonReCiPe 2016 v1.1 Endpoint (I) - Climate change Human Health, incl biogenic carbonReCiPe 2016 v1.1 Endpoint (I) - Climate change Freshw Ecosystems, incl biogenic carbonReCiPe 2016 v1.1 Endpoint (I) - Metal depletionReCiPe 2016 v1.1 Endpoint (I) - Photochemical Ozone Formation, Human HealthReCiPe 2016 v1.1 Endpoint (I) - Photochemical Ozone Formation, EcosystemsReCiPe 2016 v1.1 Endpoint (I) - Fossil depletionReCiPe 2016 v1.1 Endpoint (I) - Human toxicity, cancerReCiPe 2016 v1.1 Endpoint (I) - Freshwater Consumption, Human HealthReCiPe 2016 v1.1 Endpoint (I) - Freshwater Consumption, Terrest EcosystemsReCiPe 2016 v1.1 Endpoint (I) - Freshwater Consumption, Freshw EcosystemsReCiPe 2016 v1.1 Endpoint (I) - Stratospheric Ozone DepletionReCiPe 2016 v1.1 Endpoint (I) - Fine Particulate Matter FormationReCiPe 2016 v1.1 Endpoint (I) - Terrestrial AcidificationReCiPe 2016 v1.1 Endpoint (I) - Ionizing RadiationReCiPe 2016 v1.1 Endpoint (I) - Freshwater EutrophicationReCiPe 2016 v1.1 Endpoint (I) - Land useReCiPe 2016 v1.1 Endpoint (I) - Marine EutrophicationIPCC AR5 GWP20, incl biogenic carbonIPCC AR5 GWP100, incl biogenic carbonIPCC AR5 GTP50, incl biogenic carbonIPCC AR5 GTP20, incl biogenic carbonIPCC AR5 GTP100, incl biogenic carbonIPCC AR5 GTP20, Land Use Change only, no norm/weightIPCC AR5 GTP20, incl biogenic carbon, incl Land Use Change, no norm/weightIPCC AR5 GTP50, incl biogenic carbon, incl Land Use Change, no norm/weightIPCC AR5 GWP100, incl biogenic carbon, incl Land Use Change, no norm/weightIPCC AR5 GWP100, Land Use Change only, no norm/weightIPCC AR5 GTP100, incl biogenic carbon, incl Land Use Change, no norm/weightIPCC AR5 GTP50, Land Use Change only, no norm/weightIPCC AR5 GTP100, Land Use Change only, no norm/weightIPCC AR5 GWP20, Land Use Change only, no norm/weightIPCC AR5 GWP20, incl biogenic carbon, incl Land Use Change, no norm/weightIPCC AR5 GWP20, excl biogenic carbonIPCC AR5 GTP20, excl biogenic carbonIPCC AR5 GWP100, excl biogenic carbonIPCC AR5 GTP50, excl biogenic carbonIPCC AR5 GTP100, excl biogenic carbonIPCC AR5 GWP20, Land Use Change only, no norm/weightIPCC AR5 GTP100, Land Use Change only, no norm/weightIPCC AR5 GWP100, Land Use Change only, no norm/weightIPCC AR5 GWP100, excl biogenic carbon, incl Land Use Change, no norm/weightIPCC AR5 GTP20, Land Use Change only, no norm/weightIPCC AR5 GWP20, excl biogenic carbon, incl Land Use Change, no norm/weightIPCC AR5 GTP100, excl biogenic carbon, incl Land Use Change, no norm/weightIPCC AR5 GTP50, Land Use Change only, no norm/weightIPCC AR5 GTP50, excl biogenic carbon, incl Land Use Change, no norm/weightIPCC AR5 GTP20, excl biogenic carbon, incl Land Use Change, no norm/weightLANCA v2.3, Biotic Production Loss Potential (Occupation)LANCA v2.3, Biotic Production Loss Potential (Transformation)LANCA v2.3, Erosion Potential (Occupation)LANCA v2.3, Erosion Potential (Transformation)LANCA v2.3, Groundwater Regeneration Reduction Potential (Occupation)LANCA v2.3, Groundwater Regeneration Reduction Potential (Transformation)LANCA v2.3, Infiltration Reduction Potential (Occupation)LANCA v2.3, Infiltration Reduction Potential (Transformation)LANCA v2.3, Physicochemical Filtration Reduction Potential (Occupation)LANCA v2.3, Physicochemical Filtration Reduction Potential (Transformation)TRACI 2.1, Global Warming Air, incl. biogenic carbonTRACI 2.1, Resources, Fossil fuelsTRACI 2.1, Human toxicity, cancer (recommended)TRACI 2.1, Human toxicity, non-canc. (recommended)TRACI 2.1, Global Warming Air, excl. biogenic carbonTRACI 2.1, Smog AirTRACI 2.1, Ecotoxicity (recommended)TRACI 2.1, AcidificationTRACI 2.1, EutrophicationTRACI 2.1, Human Health Particulate AirTRACI 2.1, Ozone Depletion AirTRACI 2.1, Global Warming Air, excl biogenic carbon, incl LUC, no norm/weightTRACI 2.1, Global Warming Air, LUC only, no norm/weightTRACI 2.1, Global Warming Air, incl biogenic carbon, incl LUC, no norm/weightUBP 2013, Carcinogenic substances into airUBP 2013, Energy resourcesUBP 2013, Global warmingUBP 2013, Heavy metals into airUBP 2013, Heavy metals into soilUBP 2013, Heavy metals into waterUBP 2013, Land useUBP 2013, Main air pollutantsUBP 2013, Mineral resourcesUBP 2013, Non radioactive waste to depositUBP 2013, Ozone layer depletionUBP 2013, Pesticides into soilUBP 2013, POP into waterUBP 2013, Radioactive substances into airUBP 2013, Radioactive substances into waterUBP 2013, Radioactive waste to depositUBP 2013, Water pollutantsUBP 2013, Water resourcesUBP 2013, Global warming, incl Land Use ChangeUBP 2013, Global warming, Land Use Change onlyUSEtox 2.1, Ecotoxicity (recommended and interim)USEtox 2.1, Ecotoxicity (recommended only)USEtox 2.1, Human toxicity, cancer (recommended and interim)USEtox 2.1, Human toxicity, cancer (recommended only)USEtox 2.1, Human toxicity, non-canc. (recommended and interim)USEtox 2.1, Human toxicity, non-canc. (recommended only)AWARE, high characterization factor for unspecified waterAWARE, low characterization factor for unspecified waterAWARE, OECD+BRIC average for unspecified waterBlue water consumptionBlue water useTotal freshwater consumption (including rainwater)Total freshwater useWSI, high characterization factor for unspecified waterWSI, low characterization factor for unspecified waterWSI, OECD+BRIC average for unspecified waterAWARE (excl hydropower), high characterization factor for unspecified waterAWARE (excl hydropower), low characterization factor for unspecified waterAWARE (excl hydropower), OECD+BRIC average for unspecified waterBlue water consumption (excl hydropower)Blue water use (excl hydropower)Total freshwater consumption (excl hydropower, including rainwater)Total freshwater use (excl hydropower)WSI (excl hydropower), high characterization factor for unspecified waterWSI (excl hydropower), low characterization factor for unspecified waterWSI (excl hydropower), OECD+BRIC average for unspecified waterThe LCI method applied is in compliance with ISO 14040 and 14044. The documentation includes all relevant information in view of the data quality and scope of the application of the respective LCI result / data set. The dataset represents the state-of-the-art in view of the referenced functional unit.thinkstepIABP-GaBiIBP-GaBiOverall quality according to different validation schemes
GaBi = 1,8 interpreted into "good overall quality" in the GaBi quality validation scheme
ILCD = 1,9 interpreted into "basic overall quality" in the ILCD quality validation scheme
PEF = 1,8 interpreted into "very good overall quality" in the PEF quality validation schemeGaBi conformity systemFully compliantFully compliantFully compliantFully compliantFully compliantNot definedUNEP SETAC Life Cycle InitiativeNot definedNot definedNot definedNot definedNot definedNot definedILCD Data Network - Entry-levelNot definedFully compliantFully compliantNot definedFully compliantNot definedthinkstepThe data set represents a cradle to gate inventory. It can be used to characterise the supply chain situation of the respective commodity in a representative manner. Combination with individual unit processes using this commodity enables the generation of user-specific (product) LCAs. The data set does not necessarily fit for any possible specific supply situation - especially if significantly different technology routes exist - but is representative for a common supply chain situation.thinkstepIABP-GaBi2020-01-21T09:23:34.000ILCD format 1.1thinkstepNo official approval by producer or operator2020-01-21T09:23:34.00000.00.001Data set finalised; entirely publishedGaBi databasesthinksteptrueOtherGaBi (source code, database including extension modules and single data sets, documentation) remains property of thinkstep AG. thinkstep AG delivers GaBi licenses comprising data storage medium and manual as ordered by the customer. The license guarantees the right of use for one installation of GaBi. Further installations using the same license are not permitted. Additional licenses are only valid if the licensee holds at least one main license. Licenses are not transferable and must only be used within the licensee's organisation. Data sets may be copied for internal use. The number of copies is restricted to the number of licenses of the software system GaBi the licensee owns. The right of use is exclusively valid for the licensee. All rights reserved.2-(Perfluorohexyl)ethyl acrylateOutput1.01.00Mixed primary / secondaryMeasuredvaluable